Is The Queen of Pop the ultimate fashion muse? Having worked with everyone from Gaultier to Louis Vuitton, Madonna is adding another high-fashion campaign to her resume. Madonna will front the Spring/Summer 2010 Dolce & Gabbana promo campaign.

The 51-year-old pop star has moved on from modeling for France’s Louis Vuitton in order to work for the popular Italian fashion duo, D&G announced in its online magazine Swide on Monday.

“To have Madonna in our campaign is a dream come true,” Domenico Dolce and Stefano Gabbana said in a statement. “It seemed only fitting that Madonna, who embodies both the strong sensuality of the brand and who shares an Italian heritage with the designers should be the one to showcase the Sicilian inspired collection,” the duo remarked of their upcoming collection, which is said to heavily feature corsets.

D&G designed the costumes for Madonna’s 1993 “The Girlie Show Tour” as well as last year’s “Sticky & Sweet” trek around the globe.

Photographer Steven Klein reportedly snapped the blonde’s first ads for the label in New York City last week.