Brad Pitt organized a photoshoot of partner Angelina Jolie and their beaming brood of six that will appear in the November issue of W Magazine. Fashion Week Daily reports.

The photo-op, which took place at the couple’s chateau in the South of France last week, is Brad’s first time shooting a professional magazine cover.

The appearance will be Brangelina’s second showing for W. The couple confirmed their rumored romance in a pictorial exclusive for the Style Bible, entitled “Domestic Bliss.”